2 0 2007 byu cho 0 journal Original Byun, H. S.[Hun Soo] Choi, M.-Y.[Min-Yong] J. Chem. Thermodyn. 2007 2007-07-06 High pressure phase behaviour of the binary mixture for the 2-hydroxyethyl methacrylate, 2-hydroxypropyl acrylate, and 2-hydroxypropyl methacrylate in supercritical carbon dioxide High pressure phase behaviour Carbon dioxide 2-Hydroxyethyl methacrylate 2-Hydroxypropyl methacrylate 2-Hydroxypropyl acrylate 39 855-861 1 carbon dioxide CO2 1 Commercial source 1 99.8 3 Stated by supplier 2 None used 2 2-hydroxyethyl methacrylate C6H10O3 1 Commercial source 1 98 2 Stated by supplier 2 None used 3 2-hydroxypropyl acrylate C6H10O3 1 Commercial source 1 96 2 Stated by supplier 2 None used 4 hydroxypropyl methacrylate C7H12O3 1 Commercial source 1 98 2 Stated by supplier 2 None used 1 1 2 1 Principal objective of the work HR HR 5/8/2007 1 Critical pressure, kPa Direct measurement Liquid Direct value, X 1 Author Liquid Gas 1 Mole fraction 2 Liquid 1 .085 2 1 13620 4 1 20 1 .114 3 1 18590 4 1 20 1 .136 3 1 22280 4 1 20 1 .187 3 1 25030 4 1 20 1 .187 3 1 27100 4 1 20 1 1 2 1 Principal objective of the work HR HR 5/8/2007 1 Critical temperature, K Visual observation in an unstirred cell Liquid Direct value, X 1 Author Author Standard deviation of a single value (unbiased) Liquid Gas 1 Mole fraction 2 Liquid 1 .085 2 1 313.2 4 1 .2 5 1 1 .114 3 1 333.2 4 1 .2 5 1 1 .136 3 1 353.2 4 1 .2 5 1 1 .187 3 1 373.2 4 1 .2 5 1 1 .187 3 1 393.2 4 1 .2 5 1 1 1 2 1 Principal objective of the work HR HR 5/8/2007 1 Vapor or sublimation pressure, kPa Closed cell (Static) method Liquid Direct value, X 1 Author Liquid Gas 1 Temperature, K 1 Author 2 Mole fraction 2 Liquid 1 313.2 4 2 .114 3 1 13620 4 1 20 1 313.2 4 2 .136 3 1 13540 4 1 20 1 313.2 4 2 .187 3 1 13260 4 1 20 1 313.2 4 2 .225 3 1 12650 4 1 20 1 313.2 4 2 .292 3 1 11550 4 1 20 1 313.2 4 2 .352 3 1 10380 4 1 20 1 313.2 4 2 .425 3 1 9350 3 1 20 1 313.2 4 2 .501 3 1 8020 3 1 20 1 313.2 4 2 .557 3 1 7220 3 1 20 1 313.2 4 2 .694 3 1 5310 3 1 20 1 333.2 4 2 .136 3 1 18400 4 1 20 1 333.2 4 2 .187 3 1 17230 4 1 20 1 333.2 4 2 .225 3 1 16660 4 1 20 1 333.2 4 2 .292 3 1 15010 4 1 20 1 333.2 4 2 .352 3 1 13430 4 1 20 1 333.2 4 2 .425 3 1 11730 4 1 20 1 333.2 4 2 .501 3 1 10000 4 1 20 1 333.2 4 2 .557 3 1 9050 3 1 20 1 333.2 4 2 .694 3 1 6860 3 1 20 1 353.2 4 2 .187 3 1 21540 4 1 20 1 353.2 4 2 .225 3 1 20860 4 1 20 1 353.2 4 2 .292 3 1 18770 4 1 20 1 353.2 4 2 .352 3 1 16490 4 1 20 1 353.2 4 2 .425 3 1 14490 4 1 20 1 353.2 4 2 .501 3 1 11890 4 1 20 1 353.2 4 2 .557 3 1 11070 4 1 20 1 353.2 4 2 .694 3 1 8070 3 1 20 1 373.2 4 2 .225 3 1 24450 4 1 20 1 373.2 4 2 .292 3 1 21900 4 1 20 1 373.2 4 2 .352 3 1 18950 4 1 20 1 373.2 4 2 .425 3 1 16930 4 1 20 1 373.2 4 2 .501 3 1 13990 4 1 20 1 373.2 4 2 .557 3 1 12900 4 1 20 1 373.2 4 2 .694 3 1 9240 3 1 20 1 393.2 4 2 .225 3 1 26520 4 1 20 1 393.2 4 2 .292 3 1 24000 4 1 20 1 393.2 4 2 .352 3 1 21460 4 1 20 1 393.2 4 2 .425 3 1 18830 4 1 20 1 393.2 4 2 .501 3 1 15920 4 1 20 1 393.2 4 2 .557 3 1 14350 4 1 20 1 393.2 4 2 .694 3 1 9970 3 1 20 1 1 2 1 Principal objective of the work HR HR 5/8/2007 1 Vapor or sublimation pressure, kPa Closed cell (Static) method Gas Direct value, X 1 Author Gas Liquid 1 Temperature, K 1 Author 2 Mole fraction 2 Gas 1 333.2 4 2 .085 2 1 18000 4 1 20 1 353.2 4 2 .085 2 1 21440 4 1 20 1 353.2 4 2 .114 3 1 22210 4 1 20 1 373.2 4 2 .085 2 1 24100 4 1 20 1 373.2 4 2 .114 3 1 24790 4 1 20 1 373.2 4 2 .136 3 1 24930 4 1 20 1 393.2 4 2 .085 2 1 26410 4 1 20 1 393.2 4 2 .114 3 1 26830 4 1 20 1 393.2 4 2 .136 3 1 26790 4 1 20 1 1 3 1 Principal objective of the work HR HR 5/8/2007 1 Critical pressure, kPa Direct measurement Liquid Direct value, X 1 Author Liquid Gas 1 Mole fraction 3 Liquid 1 .088 2 1 12880 4 1 20 1 .09 2 1 18050 4 1 20 1 .126 3 1 22240 4 1 20 1 .126 3 1 24070 4 1 20 1 .165 3 1 25930 4 1 20 1 1 3 1 Principal objective of the work HR HR 5/8/2007 1 Critical temperature, K Visual observation in an unstirred cell Liquid Direct value, X 1 Author Liquid Gas 1 Mole fraction 3 Liquid 1 .088 2 1 313.2 4 1 .2 1 .09 2 1 333.2 4 1 .2 1 .126 3 1 353.2 4 1 .2 1 .126 3 1 373.2 4 1 .2 1 .165 3 1 393.2 4 1 .2 1 1 3 1 Principal objective of the work HR HR 5/8/2007 1 Vapor or sublimation pressure, kPa Closed cell (Static) method Liquid Direct value, X 1 Author Liquid Gas 1 Temperature, K 1 Author 2 Mole fraction 3 Liquid 1 313.2 4 2 .724 3 1 5210 3 1 20 1 313.2 4 2 .631 3 1 6270 3 1 20 1 333.2 4 2 .724 3 1 6420 3 1 20 1 313.2 4 2 .565 3 1 6880 3 1 20 1 353.2 4 2 .724 3 1 7510 3 1 20 1 313.2 4 2 .485 3 1 7590 3 1 20 1 333.2 4 2 .631 3 1 8080 3 1 20 1 313.2 4 2 .446 3 1 8220 3 1 20 1 373.2 4 2 .724 3 1 8490 3 1 20 1 333.2 4 2 .565 3 1 9040 3 1 20 1 313.2 4 2 .375 3 1 9220 3 1 20 1 393.2 4 2 .724 3 1 9280 3 1 20 1 313.2 4 2 .348 3 1 9600 3 1 20 1 353.2 4 2 .631 3 1 9790 3 1 20 1 313.2 4 2 .318 3 1 9830 3 1 20 1 313.2 4 2 .283 3 1 10230 4 1 20 1 333.2 4 2 .485 3 1 10500 4 1 20 1 313.2 4 2 .251 3 1 10780 4 1 20 1 373.2 4 2 .631 3 1 11190 4 1 20 1 353.2 4 2 .565 3 1 11220 4 1 20 1 333.2 4 2 .446 3 1 11270 4 1 20 1 313.2 4 2 .209 3 1 11360 4 1 20 1 313.2 4 2 .165 3 1 12010 4 1 20 1 393.2 4 2 .631 3 1 12480 4 1 20 1 333.2 4 2 .375 3 1 12700 4 1 20 1 313.2 4 2 .126 3 1 12720 4 1 20 1 353.2 4 2 .485 3 1 12820 4 1 20 1 313.2 4 2 .09 2 1 12860 4 1 20 1 373.2 4 2 .565 3 1 12920 4 1 20 1 333.2 4 2 .348 3 1 13100 4 1 20 1 333.2 4 2 .318 3 1 13740 4 1 20 1 353.2 4 2 .446 3 1 14180 4 1 20 1 393.2 4 2 .565 3 1 14260 4 1 20 1 333.2 4 2 .283 3 1 14500 4 1 20 1 373.2 4 2 .485 3 1 14900 4 1 20 1 333.2 4 2 .251 3 1 15120 4 1 20 1 353.2 4 2 .375 3 1 15670 4 1 20 1 333.2 4 2 .209 3 1 16190 4 1 20 1 373.2 4 2 .446 3 1 16380 4 1 20 1 393.2 4 2 .485 3 1 16420 4 1 20 1 353.2 4 2 .348 3 1 16550 4 1 20 1 353.2 4 2 .318 3 1 16970 4 1 20 1 333.2 4 2 .165 3 1 17260 4 1 20 1 393.2 4 2 .446 3 1 17830 4 1 20 1 333.2 4 2 .126 3 1 17940 4 1 20 1 353.2 4 2 .283 3 1 18070 4 1 20 1 373.2 4 2 .375 3 1 18100 4 1 20 1 373.2 4 2 .348 3 1 18790 4 1 20 1 353.2 4 2 .251 3 1 19210 4 1 20 1 373.2 4 2 .318 3 1 19760 4 1 20 1 393.2 4 2 .375 3 1 20030 4 1 20 1 353.2 4 2 .209 3 1 20690 4 1 20 1 393.2 4 2 .348 3 1 20760 4 1 20 1 373.2 4 2 .283 3 1 20790 4 1 20 1 353.2 4 2 .165 3 1 21580 4 1 20 1 393.2 4 2 .318 3 1 21590 4 1 20 1 373.2 4 2 .251 3 1 21590 4 1 20 1 393.2 4 2 .283 3 1 22760 4 1 20 1 373.2 4 2 .209 3 1 22930 4 1 20 1 393.2 4 2 .251 3 1 23720 4 1 20 1 373.2 4 2 .165 3 1 24000 4 1 20 1 393.2 4 2 .209 3 1 24660 4 1 20 1 1 3 1 Principal objective of the work HR HR 5/8/2007 1 Vapor or sublimation pressure, kPa Closed cell (Static) method Gas Direct value, X 1 Author Gas Liquid 1 Temperature, K 1 Author 2 Mole fraction 3 Gas 1 333.2 4 2 .088 2 1 17890 4 1 20 1 353.2 4 2 .088 2 1 21430 4 1 20 1 353.2 4 2 .09 2 1 21560 4 1 20 1 373.2 4 2 .088 2 1 23240 4 1 20 1 373.2 4 2 .09 2 1 23620 4 1 20 1 393.2 4 2 .088 2 1 25070 4 1 20 1 393.2 4 2 .09 2 1 25310 4 1 20 1 393.2 4 2 .126 3 1 25720 4 1 20 1 1 4 1 Principal objective of the work HR HR 5/8/2007 1 Critical pressure, kPa Direct measurement Liquid Direct value, X 1 Author Liquid Gas 1 Mole fraction 4 Liquid 1 .038 2 1 9370 3 1 20 1 .068 2 1 18470 4 1 20 1 .108 3 1 23620 4 1 20 1 1 4 1 Principal objective of the work HR HR 5/8/2007 1 Critical temperature, K Visual observation in an unstirred cell Liquid Direct value, X 1 Author Liquid Gas 1 Mole fraction 4 Liquid 1 .038 2 1 313.2 4 1 .2 1 .068 2 1 353.2 4 1 .2 1 .108 3 1 393.2 4 1 .2 1 1 4 1 Principal objective of the work HR HR 5/8/2007 1 Vapor or sublimation pressure, kPa Closed cell (Static) method Liquid Direct value, X 1 Author Liquid Gas 1 Temperature, K 1 Author 2 Mole fraction 4 Liquid 1 313.2 4 2 .058 2 1 9320 3 1 20 1 313.2 4 2 .068 2 1 9340 3 1 20 1 313.2 4 2 .108 3 1 9260 3 1 20 1 313.2 4 2 .158 3 1 9070 3 1 20 1 313.2 4 2 .196 3 1 8990 3 1 20 1 313.2 4 2 .294 3 1 8190 3 1 20 1 313.2 4 2 .331 3 1 7830 3 1 20 1 313.2 4 2 .408 3 1 7310 3 1 20 1 313.2 4 2 .477 3 1 6830 3 1 20 1 313.2 4 2 .586 3 1 5830 3 1 20 1 313.2 4 2 .662 3 1 4940 3 1 20 1 313.2 4 2 .747 3 1 4230 3 1 20 1 333.2 4 2 .068 2 1 14340 4 1 20 1 333.2 4 2 .108 3 1 14340 4 1 20 1 333.2 4 2 .158 3 1 13740 4 1 20 1 333.2 4 2 .196 3 1 13010 4 1 20 1 333.2 4 2 .294 3 1 11690 4 1 20 1 333.2 4 2 .331 3 1 10790 4 1 20 1 333.2 4 2 .408 3 1 9860 3 1 20 1 333.2 4 2 .477 3 1 8780 3 1 20 1 333.2 4 2 .586 3 1 7240 3 1 20 1 333.2 4 2 .662 3 1 6030 3 1 20 1 333.2 4 2 .747 3 1 5300 3 1 20 1 353.2 4 2 .108 3 1 18460 4 1 20 1 353.2 4 2 .158 3 1 18150 4 1 20 1 353.2 4 2 .196 3 1 17190 4 1 20 1 353.2 4 2 .294 3 1 14690 4 1 20 1 353.2 4 2 .331 3 1 13830 4 1 20 1 353.2 4 2 .408 3 1 12520 4 1 20 1 353.2 4 2 .477 3 1 10750 4 1 20 1 353.2 4 2 .586 3 1 8680 3 1 20 1 353.2 4 2 .662 3 1 7130 3 1 20 1 353.2 4 2 .747 3 1 6040 3 1 20 1 373.2 4 2 .108 3 1 21480 4 1 20 1 373.2 4 2 .158 3 1 21190 4 1 20 1 373.2 4 2 .196 3 1 20070 4 1 20 1 373.2 4 2 .294 3 1 17410 4 1 20 1 373.2 4 2 .331 3 1 16480 4 1 20 1 373.2 4 2 .408 3 1 14340 4 1 20 1 373.2 4 2 .477 3 1 12470 4 1 20 1 373.2 4 2 .586 3 1 9820 3 1 20 1 373.2 4 2 .662 3 1 8120 3 1 20 1 373.2 4 2 .747 3 1 6650 3 1 20 1 393.2 4 2 .158 3 1 23360 4 1 20 1 393.2 4 2 .196 3 1 22260 4 1 20 1 393.2 4 2 .294 3 1 19450 4 1 20 1 393.2 4 2 .331 3 1 18590 4 1 20 1 393.2 4 2 .408 3 1 16030 4 1 20 1 393.2 4 2 .477 3 1 14210 4 1 20 1 393.2 4 2 .586 3 1 10990 4 1 20 1 393.2 4 2 .662 3 1 9110 3 1 20 1 393.2 4 2 .747 3 1 7030 3 1 20 1 1 4 1 Principal objective of the work HR HR 5/8/2007 1 Vapor or sublimation pressure, kPa Closed cell (Static) method Gas Direct value, X 1 Author Gas Liquid 1 Temperature, K 1 Author 2 Mole fraction 4 Gas 1 313.2 4 2 .018 2 1 9360 3 1 20 1 333.2 4 2 .018 2 1 11790 4 1 20 1 333.2 4 2 .038 2 1 13660 4 1 20 1 333.2 4 2 .058 2 1 14100 4 1 20 1 353.2 4 2 .018 2 1 14540 4 1 20 1 373.2 4 2 .018 2 1 16860 4 1 20 1 353.2 4 2 .038 2 1 17410 4 1 20 1 393.2 4 2 .018 2 1 17520 4 1 20 1 353.2 4 2 .058 2 1 18220 4 1 20 1 373.2 4 2 .038 2 1 19930 4 1 20 1 373.2 4 2 .058 2 1 20740 4 1 20 1 373.2 4 2 .068 2 1 21070 4 1 20 1 393.2 4 2 .038 2 1 21690 4 1 20 1 393.2 4 2 .058 2 1 22860 4 1 20 1 393.2 4 2 .068 2 1 23140 4 1 20