2 0 2009 szw sta 0 journal Original Szwajczak, E.[Elzbieta] Stagraczynski, R.[Ryszard] Herba, H.[Henryk] Swiergiel, J.[Jolanta] Jadzyn, J.[Jan] J. Chem. Eng. Data 2009 2009-02-25 Shear Viscosity of Mixtures of r-Tocopherol with Nonpolar Solvents Shear viscosities ( A) of the binary mixtures of R-tocopherol (vitamin E) with 4-n-propylcyclohexyl-4 -npentylphenyl and mesitilene, two nonpolar solvents composed of the molecules of essentially different shape, have been measured in the temperature range from (278 to 353) K. In the whole concentration range of R-tocopherol in both solvents, the dependence of A on T can be well described by the Vogel-Fulcher-Tammann equation. The viscosity deviations from the additive behavior are strongly negative, and their concentration dependence was fitted to the Redlich-Kister equation. 10.1021/je800439e 54 400-404 1 dl-.alpha.-tocopherol C29H50O2 1 Commercial source 1 97 2 Stated by supplier 2 None used 2 1,3,5-trimethylbenzene C9H12 1 Commercial source 1 98 2 Stated by supplier 2 None used 3 1-pentyl-4-(4-propylcyclohexyl)-benzene C20H32 1 Synthesized by others 1 99 2 Stated by supplier 2 Unspecified 1 1 Principal objective of the work RDC TRC 2/24/2009 1 Viscosity, Pa*s Cone and plate viscometry Liquid Direct value, X 1 Author Liquid 1 Temperature, K 1 Author 2 Pressure, kPa 1 278.15 5 2 101 3 1 37.128 5 1 .111384 1 296.15 5 2 101 3 1 3.0175 5 1 .0090525 1 314.15 5 2 101 3 1 .45458 5 1 .00136374 1 330.15 5 2 101 3 1 .1292 5 1 .0003876 1 345.15 5 2 101 3 1 .04998 4 1 .00014994 1 284.15 5 2 101 3 1 15.242 5 1 .045726 1 302.15 5 2 101 3 1 1.531 5 1 .004593 1 320.15 5 2 101 3 1 .28356 5 1 .00085068 1 335.15 5 2 101 3 1 .09265 4 1 .00027795 1 350.15 5 2 101 3 1 .0374 4 1 .0001122 1 290.15 5 2 101 3 1 6.38 5 1 .01914 1 308.15 5 2 101 3 1 .81481 5 1 .00244443 1 325.15 5 2 101 3 1 .18751 5 1 .00056253 1 340.15 5 2 101 3 1 .06732 4 1 .00020196 1 290.15 5 2 101 3 1 6.3801 5 1 .0191403 2 1 Principal objective of the work RDC TRC 2/24/2009 1 Viscosity, Pa*s Cone and plate viscometry Liquid Direct value, X 1 Author Liquid 1 Temperature, K 1 Author 2 Pressure, kPa 1 278.15 5 2 101 3 1 .00085 2 1 .00000255 1 296.15 5 2 101 3 1 .00063 2 1 .00000189 1 314.15 5 2 101 3 1 .00049 2 1 .00000147 1 330.15 5 2 101 3 1 .00041 2 1 .00000123 1 345.15 5 2 101 3 1 .00035 2 1 .00000105 1 284.15 5 2 101 3 1 .0008 2 1 .0000024 1 302.15 5 2 101 3 1 .00057 2 1 .00000171 1 320.15 5 2 101 3 1 .00046 2 1 .00000138 1 335.15 5 2 101 3 1 .0004 2 1 .0000012 1 350.15 5 2 101 3 1 .00034 2 1 .00000102 1 290.15 5 2 101 3 1 .00075 2 1 .00000225 1 308.15 5 2 101 3 1 .00053 2 1 .00000159 1 325.15 5 2 101 3 1 .00044 2 1 .00000132 1 340.15 5 2 101 3 1 .00039 2 1 .00000117 3 1 Principal objective of the work RDC TRC 2/24/2009 1 Viscosity, Pa*s Cone and plate viscometry Liquid Direct value, X 1 Author Liquid 1 Temperature, K 1 Author 2 Pressure, kPa 1 278.15 5 2 101 3 1 .02774 4 1 .00008322 1 296.15 5 2 101 3 1 .0135 4 1 .0000405 1 314.15 5 2 101 3 1 .00764 3 1 .00002292 1 330.15 5 2 101 3 1 .00519 3 1 .00001557 1 345.15 5 2 101 3 1 .00368 3 1 .00001104 1 284.15 5 2 101 3 1 .02148 4 1 .00006444 1 302.15 5 2 101 3 1 .01109 4 1 .00003327 1 320.15 5 2 101 3 1 .00658 3 1 .00001974 1 335.15 5 2 101 3 1 .00457 3 1 .00001371 1 350.15 5 2 101 3 1 .00329 3 1 .00000987 1 290.15 5 2 101 3 1 .01695 4 1 .00005085 1 308.15 5 2 101 3 1 .00921 3 1 .00002763 1 325.15 5 2 101 3 1 .00601 3 1 .00001803 1 340.15 5 2 101 3 1 .00413 3 1 .00001239 1 1 3 1 Principal objective of the work KRP TRC 2/18/2009 1 Viscosity, Pa*s Cone and plate viscometry Liquid Direct value, X 1 Author Liquid Pressure, kPa 101 3 1 Mole fraction 1 Liquid 2 Temperature, K 1 Author 1 0 0 2 278.15 5 1 .02774 4 1 .00008322 1 .2058 4 2 278.15 5 1 .07595 4 1 .00022785 1 .4023 4 2 278.15 5 1 .38428 5 1 .00115284 1 .6026 4 2 278.15 5 1 1.2706 5 1 .0038118 1 .8018 4 2 278.15 5 1 7.4719 5 1 .0224157 1 1 5 2 278.15 5 1 37.128 5 1 .111384 1 0 0 2 296.15 5 1 .0135 4 1 .0000405 1 .2058 4 2 296.15 5 1 .0281 4 1 .0000843 1 .4023 4 2 296.15 5 1 .09637 4 1 .00028911 1 .6026 4 2 296.15 5 1 .26641 5 1 .00079923 1 .8018 4 2 296.15 5 1 .91116 5 1 .00273348 1 1 5 2 296.15 5 1 3.0175 5 1 .0090525 1 0 0 2 314.15 5 1 .00764 3 1 .00002292 1 .2058 4 2 314.15 5 1 .01317 4 1 .00003951 1 .4023 4 2 314.15 5 1 .03391 4 1 .00010173 1 .6026 4 2 314.15 5 1 .07105 4 1 .00021315 1 .8018 4 2 314.15 5 1 .17309 5 1 .00051927 1 1 5 2 314.15 5 1 .45458 5 1 .00136374 1 0 0 2 330.15 5 1 .00519 3 1 .00001557 1 .2058 4 2 330.15 5 1 .00798 3 1 .00002394 1 .4023 4 2 330.15 5 1 .01686 4 1 .00005058 1 .6026 4 2 330.15 5 1 .0302 4 1 .0000906 1 .8018 4 2 330.15 5 1 .06104 4 1 .00018312 1 1 5 2 330.15 5 1 .1292 5 1 .0003876 1 0 0 2 345.15 5 1 .00368 3 1 .00001104 1 .2058 4 2 345.15 5 1 .00537 3 1 .00001611 1 .4023 4 2 345.15 5 1 .00997 3 1 .00002991 1 .6026 4 2 345.15 5 1 .0161 4 1 .0000483 1 .8018 4 2 345.15 5 1 .02732 4 1 .00008196 1 1 5 2 345.15 5 1 .04998 4 1 .00014994 1 0 0 2 284.15 5 1 .02148 4 1 .00006444 1 .2058 4 2 284.15 5 1 .05348 4 1 .00016044 1 .4023 4 2 284.15 5 1 .2316 5 1 .0006948 1 .6026 4 2 284.15 5 1 .79438 5 1 .00238314 1 .8018 4 2 284.15 5 1 3.4882 5 1 .0104646 1 1 5 2 284.15 5 1 15.242 5 1 .045726 1 0 0 2 302.15 5 1 .01109 4 1 .00003327 1 .2058 4 2 302.15 5 1 .02157 4 1 .00006471 1 .4023 4 2 302.15 5 1 .06592 4 1 .00019776 1 .6026 4 2 302.15 5 1 .16327 5 1 .00048981 1 .8018 4 2 302.15 5 1 .48533 5 1 .00145599 1 1 5 2 302.15 5 1 1.531 5 1 .004593 1 0 0 2 320.15 5 1 .00658 3 1 .00001974 1 .2058 4 2 320.15 5 1 .01098 4 1 .00003294 1 .4023 4 2 320.15 5 1 .02601 4 1 .00007803 1 .6026 4 2 320.15 5 1 .05166 4 1 .00015498 1 .8018 4 2 320.15 5 1 .12077 5 1 .00036231 1 1 5 2 320.15 5 1 .28356 5 1 .00085068 1 0 0 2 335.15 5 1 .00457 3 1 .00001371 1 .2058 4 2 335.15 5 1 .00685 3 1 .00002055 1 .4023 4 2 335.15 5 1 .01403 4 1 .00004209 1 .6026 4 2 335.15 5 1 .02408 4 1 .00007224 1 .8018 4 2 335.15 5 1 .04615 4 1 .00013845 1 1 5 2 335.15 5 1 .09265 4 1 .00027795 1 0 0 2 350.15 5 1 .00329 3 1 .00000987 1 .2058 4 2 350.15 5 1 .0047 3 1 .0000141 1 .4023 4 2 350.15 5 1 .00855 3 1 .00002565 1 .6026 4 2 350.15 5 1 .0133 4 1 .0000399 1 .8018 4 2 350.15 5 1 .02224 4 1 .00006672 1 1 5 2 350.15 5 1 .0374 4 1 .0001122 1 0 0 2 290.15 5 1 .01695 4 1 .00005085 1 .2058 4 2 290.15 5 1 .03825 4 1 .00011475 1 .4023 4 2 290.15 5 1 .14552 5 1 .00043656 1 .6026 4 2 290.15 5 1 .44194 5 1 .00132582 1 .8018 4 2 290.15 5 1 1.6699 5 1 .0050097 1 1 5 2 290.15 5 1 6.38 5 1 .01914 1 0 0 2 308.15 5 1 .00921 3 1 .00002763 1 .2058 4 2 308.15 5 1 .0168 4 1 .0000504 1 .4023 4 2 308.15 5 1 .04614 4 1 .00013842 1 .6026 4 2 308.15 5 1 .10633 5 1 .00031899 1 .8018 4 2 308.15 5 1 .27853 5 1 .00083559 1 1 5 2 308.15 5 1 .81481 5 1 .00244443 1 0 0 2 325.15 5 1 .00601 3 1 .00001803 1 .2058 4 2 325.15 5 1 .00933 3 1 .00002799 1 .4023 4 2 325.15 5 1 .02065 4 1 .00006195 1 .6026 4 2 325.15 5 1 .03936 4 1 .00011808 1 .8018 4 2 325.15 5 1 .08286 4 1 .00024858 1 1 5 2 325.15 5 1 .18751 5 1 .00056253 1 0 0 2 340.15 5 1 .00413 3 1 .00001239 1 .2058 4 2 340.15 5 1 .00604 3 1 .00001812 1 .4023 4 2 340.15 5 1 .01175 4 1 .00003525 1 .6026 4 2 340.15 5 1 .01947 4 1 .00005841 1 .8018 4 2 340.15 5 1 .03524 4 1 .00010572 1 1 5 2 340.15 5 1 .06732 4 1 .00020196 2 1 1 1 Principal objective of the work KRP TRC 2/18/2009 1 Viscosity, Pa*s Cone and plate viscometry Liquid Direct value, X 1 Author Liquid Pressure, kPa 101 3 1 Mole fraction 1 Liquid 2 Temperature, K 1 Author 1 0 0 2 278.15 5 1 .00085 2 1 .00000255 1 .2025 4 2 278.15 5 1 .00685 3 1 .00002055 1 .4036 4 2 278.15 5 1 .14808 5 1 .00044424 1 .5972 4 2 278.15 5 1 1.2536 5 1 .0037608 1 .7955 4 2 278.15 5 1 5.9447 5 1 .0178341 1 1 5 2 278.15 5 1 37.128 5 1 .111384 1 0 0 2 296.15 5 1 .00063 2 1 .00000189 1 .2025 4 2 296.15 5 1 .00388 3 1 .00001164 1 .4036 4 2 296.15 5 1 .038 4 1 .000114 1 .5972 4 2 296.15 5 1 .21082 5 1 .00063246 1 .7955 4 2 296.15 5 1 .81967 5 1 .00245901 1 1 5 2 296.15 5 1 3.0175 5 1 .0090525 1 0 0 2 314.15 5 1 .00049 2 1 .00000147 1 .2025 4 2 314.15 5 1 .00239 3 1 .00000717 1 .4036 4 2 314.15 5 1 .01443 4 1 .00004329 1 .5972 4 2 314.15 5 1 .05552 4 1 .00016656 1 .7955 4 2 314.15 5 1 .17398 5 1 .00052194 1 1 5 2 314.15 5 1 .45458 5 1 .00136374 1 0 0 2 330.15 5 1 .00041 2 1 .00000123 1 .2025 4 2 330.15 5 1 .00183 3 1 .00000549 1 .4036 4 2 330.15 5 1 .00775 3 1 .00002325 1 .5972 4 2 330.15 5 1 .02373 4 1 .00007119 1 .7955 4 2 330.15 5 1 .0601 4 1 .0001803 1 1 5 2 330.15 5 1 .1292 5 1 .0003876 1 0 0 2 345.15 5 1 .00035 2 1 .00000105 1 .2025 4 2 345.15 5 1 .00152 3 1 .00000456 1 .4036 4 2 345.15 5 1 .00481 3 1 .00001443 1 .5972 4 2 345.15 5 1 .01233 4 1 .00003699 1 .7955 4 2 345.15 5 1 .02647 4 1 .00007941 1 1 5 2 345.15 5 1 .04998 4 1 .00014994 1 0 0 2 284.15 5 1 .0008 2 1 .0000024 1 .2025 4 2 284.15 5 1 .00555 3 1 .00001665 1 .4036 4 2 284.15 5 1 .09232 4 1 .00027696 1 .5972 4 2 284.15 5 1 .65851 5 1 .00197553 1 .7955 4 2 284.15 5 1 3.0376 5 1 .0091128 1 1 5 2 284.15 5 1 15.242 5 1 .045726 1 0 0 2 302.15 5 1 .00057 2 1 .00000171 1 .2025 4 2 302.15 5 1 .00324 3 1 .00000972 1 .4036 4 2 302.15 5 1 .02665 4 1 .00007995 1 .5972 4 2 302.15 5 1 .13099 5 1 .00039297 1 .7955 4 2 302.15 5 1 .47736 5 1 .00143208 1 1 5 2 302.15 5 1 1.531 5 1 .004593 1 0 0 2 320.15 5 1 .00046 2 1 .00000138 1 .2025 4 2 320.15 5 1 .00214 3 1 .00000642 1 .4036 4 2 320.15 5 1 .01142 4 1 .00003426 1 .5972 4 2 320.15 5 1 .04057 4 1 .00012171 1 .7955 4 2 320.15 5 1 .116 5 1 .000348 1 1 5 2 320.15 5 1 .28356 5 1 .00085068 1 0 0 2 335.15 5 1 .0004 2 1 .0000012 1 .2025 4 2 335.15 5 1 .00172 3 1 .00000516 1 .4036 4 2 335.15 5 1 .00656 3 1 .00001968 1 .5972 4 2 335.15 5 1 .01889 4 1 .00005667 1 .7955 4 2 335.15 5 1 .04563 4 1 .00013689 1 1 5 2 335.15 5 1 .09265 4 1 .00027795 1 0 0 2 350.15 5 1 .00034 2 1 .00000102 1 .2025 4 2 350.15 5 1 .00137 3 1 .00000411 1 .4036 4 2 350.15 5 1 .00425 3 1 .00001275 1 .5972 4 2 350.15 5 1 .0105 4 1 .0000315 1 .7955 4 2 350.15 5 1 .02144 4 1 .00006432 1 1 5 2 350.15 5 1 .0374 4 1 .0001122 1 0 0 2 290.15 5 1 .00075 2 1 .00000225 1 .2025 4 2 290.15 5 1 .0046 3 1 .0000138 1 .4036 4 2 290.15 5 1 .05698 4 1 .00017094 1 .5972 4 2 290.15 5 1 .35726 5 1 .00107178 1 .7955 4 2 290.15 5 1 1.5332 5 1 .0045996 1 1 5 2 290.15 5 1 6.3801 5 1 .0191403 1 0 0 2 308.15 5 1 .00053 2 1 .00000159 1 .2025 4 2 308.15 5 1 .00294 3 1 .00000882 1 .4036 4 2 308.15 5 1 .01906 4 1 .00005718 1 .5972 4 2 308.15 5 1 .08396 4 1 .00025188 1 .7955 4 2 308.15 5 1 .27612 5 1 .00082836 1 1 5 2 308.15 5 1 .81481 5 1 .00244443 1 0 0 2 325.15 5 1 .00044 2 1 .00000132 1 .2025 4 2 325.15 5 1 .00196 3 1 .00000588 1 .4036 4 2 325.15 5 1 .00928 3 1 .00002784 1 .5972 4 2 325.15 5 1 .03055 4 1 .00009165 1 .7955 4 2 325.15 5 1 .08201 4 1 .00024603 1 1 5 2 325.15 5 1 .18751 5 1 .00056253 1 0 0 2 340.15 5 1 .00039 2 1 .00000117 1 .2025 4 2 340.15 5 1 .00165 3 1 .00000495 1 .4036 4 2 340.15 5 1 .00559 3 1 .00001677 1 .5972 4 2 340.15 5 1 .01533 4 1 .00004599 1 .7955 4 2 340.15 5 1 .03446 4 1 .00010338 1 1 5 2 340.15 5 1 .06732 4 1 .00020196