2
0
2009
cos
gar
0
journal
Original
Costa, H. F.[Henrique F.]
Gardas, R. L.[Ramesh L.]
Johnson, I.[Irudayaraj]
Fonseca, I. M. A.[Isabel M. A.]
Ferreira, A. G. M.[Abel G. M.]
J. Chem. Eng. Data
2009
2009-02-25
PVT Property Measurements for Ethyl Propionate, Ethyl Butyrate, and Ethyl Pentanoate Esters from (298 to 393) K and up to 35 MPa
The results of PVT measurements of the liquid phase within the temperature range (298 to 393) K and up to 35 MPa are presented for some aliphatic esters. Measurements were made by means of a vibrating tube densimeter, model DMA 512P from Anton Parr. The calibration of the densimeter was performed with water and n-heptane as reference fluids. The experimental PVT data have been correlated by a Tait equation. This equation gives good results when used to predict the density of the esters using the method proposed by Thomson et al. Isothermal compressibilities, isobaric expansivities, thermal pressure coefficients, and changes in the isobaric heat capacity have been calculated from the Tait equation.
10.1021/je800251v
54
256-262
1
heptane
C7H16
1
Commercial source
1
99
2
Stated by supplier
2
Fractional distillation
2
water
H2O
1
Commercial source
1
99.9
3
Estimated by the compiler
3
ethyl propanoate
C5H10O2
1
Commercial source
1
99
2
Stated by supplier
4
ethyl butanoate
C6H12O2
1
Commercial source
1
99
2
Stated by supplier
5
ethyl pentanoate
C7H14O2
1
Commercial source
1
99
2
Stated by supplier
3
1
Principal objective of the work
VN
TRC
2/20/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
Liquid
1
Pressure, kPa
1
Author
2
Temperature, K
1
Author
1
100
3
2
298.15
5
1
884.3
4
1
100
3
2
303.15
5
1
878.5
4
1
100
3
2
308.15
5
1
872.7
4
1
100
3
2
313.15
5
1
866.8
4
1
100
3
2
318.15
5
1
860.9
4
1
100
3
2
323.15
5
1
854.9
4
1
100
3
2
328.15
5
1
849.2
4
1
100
3
2
333.15
5
1
843.1
4
1
100
3
2
338.15
5
1
836.9
4
1
100
3
2
343.15
5
1
831.1
4
1
100
3
2
348.15
5
1
824.9
4
1
100
3
2
353.15
5
1
818.7
4
1
100
3
2
363.15
5
1
803.5
4
1
100
3
2
373.15
5
1
790.9
4
1
1000
4
2
298.15
5
1
884.8
4
1
1000
4
2
303.15
5
1
879
4
1
1000
4
2
308.15
5
1
873.2
4
1
1000
4
2
313.15
5
1
867.4
4
1
1000
4
2
318.15
5
1
861.5
4
1
1000
4
2
323.15
5
1
856
4
1
1000
4
2
328.15
5
1
850.2
4
1
1000
4
2
333.15
5
1
844.2
4
1
1000
4
2
338.15
5
1
838.2
4
1
1000
4
2
343.15
5
1
832.2
4
1
1000
4
2
348.15
5
1
826
4
1
1000
4
2
353.15
5
1
819.9
4
1
1000
4
2
363.15
5
1
805.1
4
1
1000
4
2
373.15
5
1
792.6
4
1
1000
4
2
383.15
5
1
780
4
1
1000
4
2
393.15
5
1
766.4
4
1
2000
4
2
298.15
5
1
885.7
4
1
2000
4
2
303.15
5
1
880
4
1
2000
4
2
308.15
5
1
874.2
4
1
2000
4
2
313.15
5
1
868.4
4
1
2000
4
2
318.15
5
1
862.6
4
1
2000
4
2
323.15
5
1
857.1
4
1
2000
4
2
328.15
5
1
851.3
4
1
2000
4
2
333.15
5
1
845.4
4
1
2000
4
2
338.15
5
1
839.5
4
1
2000
4
2
343.15
5
1
833.5
4
1
2000
4
2
348.15
5
1
827.4
4
1
2000
4
2
353.15
5
1
821.3
4
1
2000
4
2
363.15
5
1
806.9
4
1
2000
4
2
373.15
5
1
794.5
4
1
2000
4
2
383.15
5
1
782.1
4
1
2000
4
2
393.15
5
1
768.7
4
1
3000
4
2
298.15
5
1
886.6
4
1
3000
4
2
303.15
5
1
880.9
4
1
3000
4
2
308.15
5
1
875.2
4
1
3000
4
2
313.15
5
1
869.4
4
1
3000
4
2
318.15
5
1
863.7
4
1
3000
4
2
323.15
5
1
858.1
4
1
3000
4
2
328.15
5
1
852.5
4
1
3000
4
2
333.15
5
1
846.6
4
1
3000
4
2
338.15
5
1
840.7
4
1
3000
4
2
343.15
5
1
834.8
4
1
3000
4
2
348.15
5
1
828.8
4
1
3000
4
2
353.15
5
1
822.7
4
1
3000
4
2
363.15
5
1
808.7
4
1
3000
4
2
373.15
5
1
796.4
4
1
3000
4
2
383.15
5
1
784.1
4
1
3000
4
2
393.15
5
1
770.8
4
1
3340
4
2
298.15
5
1
886.9
4
1
3340
4
2
303.15
5
1
881.2
4
1
3340
4
2
308.15
5
1
875.5
4
1
3340
4
2
313.15
5
1
869.8
4
1
3340
4
2
318.15
5
1
864.1
4
1
3340
4
2
323.15
5
1
858.4
4
1
3340
4
2
328.15
5
1
852.9
4
1
3340
4
2
333.15
5
1
847
4
1
3340
4
2
338.15
5
1
841.1
4
1
3340
4
2
343.15
5
1
835.2
4
1
3340
4
2
348.15
5
1
829.3
4
1
3340
4
2
353.15
5
1
823.2
4
1
3340
4
2
363.15
5
1
809.3
4
1
3340
4
2
373.15
5
1
797.1
4
1
3340
4
2
383.15
5
1
784.8
4
1
3340
4
2
393.15
5
1
771.5
4
1
5000
4
2
298.15
5
1
888.7
4
1
5000
4
2
303.15
5
1
883
4
1
5000
4
2
308.15
5
1
877.4
4
1
5000
4
2
313.15
5
1
871.7
4
1
5000
4
2
318.15
5
1
866.1
4
1
5000
4
2
323.15
5
1
860.3
4
1
5000
4
2
328.15
5
1
854.7
4
1
5000
4
2
333.15
5
1
849
4
1
5000
4
2
338.15
5
1
843.1
4
1
5000
4
2
343.15
5
1
837.4
4
1
5000
4
2
348.15
5
1
831.5
4
1
5000
4
2
353.15
5
1
825.6
4
1
5000
4
2
363.15
5
1
812
4
1
5000
4
2
373.15
5
1
800
4
1
5000
4
2
383.15
5
1
787.9
4
1
5000
4
2
393.15
5
1
775
4
1
10000
5
2
298.15
5
1
892.9
4
1
10000
5
2
303.15
5
1
887.4
4
1
10000
5
2
308.15
5
1
882
4
1
10000
5
2
313.15
5
1
876.5
4
1
10000
5
2
318.15
5
1
871
4
1
10000
5
2
323.15
5
1
865.4
4
1
10000
5
2
328.15
5
1
860
4
1
10000
5
2
333.15
5
1
854.6
4
1
10000
5
2
338.15
5
1
848.8
4
1
10000
5
2
343.15
5
1
843.4
4
1
10000
5
2
348.15
5
1
837.7
4
1
10000
5
2
353.15
5
1
832.1
4
1
10000
5
2
363.15
5
1
819.6
4
1
10000
5
2
373.15
5
1
808.2
4
1
10000
5
2
383.15
5
1
796.6
4
1
10000
5
2
393.15
5
1
784.5
4
1
15000
5
2
298.15
5
1
896.9
4
1
15000
5
2
303.15
5
1
891.6
4
1
15000
5
2
308.15
5
1
886.3
4
1
15000
5
2
313.15
5
1
880.9
4
1
15000
5
2
318.15
5
1
875.6
4
1
15000
5
2
323.15
5
1
870.2
4
1
15000
5
2
328.15
5
1
865
4
1
15000
5
2
333.15
5
1
859.7
4
1
15000
5
2
338.15
5
1
854.4
4
1
15000
5
2
343.15
5
1
848.9
4
1
15000
5
2
348.15
5
1
843.4
4
1
15000
5
2
353.15
5
1
838
4
1
15000
5
2
363.15
5
1
826.5
4
1
15000
5
2
373.15
5
1
815.6
4
1
15000
5
2
383.15
5
1
804.6
4
1
15000
5
2
393.15
5
1
793.1
4
1
20000
5
2
298.15
5
1
900.7
4
1
20000
5
2
303.15
5
1
895.6
4
1
20000
5
2
308.15
5
1
890.4
4
1
20000
5
2
313.15
5
1
885.1
4
1
20000
5
2
318.15
5
1
880
4
1
20000
5
2
323.15
5
1
874.7
4
1
20000
5
2
328.15
5
1
869.6
4
1
20000
5
2
333.15
5
1
864.5
4
1
20000
5
2
338.15
5
1
859.4
4
1
20000
5
2
343.15
5
1
854
4
1
20000
5
2
348.15
5
1
848.8
4
1
20000
5
2
353.15
5
1
843.5
4
1
20000
5
2
363.15
5
1
833
4
1
20000
5
2
373.15
5
1
822.5
4
1
20000
5
2
383.15
5
1
811.9
4
1
20000
5
2
393.15
5
1
800.8
4
1
25000
5
2
298.15
5
1
904.4
4
1
25000
5
2
303.15
5
1
899.4
4
1
25000
5
2
308.15
5
1
894.3
4
1
25000
5
2
313.15
5
1
889.3
4
1
25000
5
2
318.15
5
1
884.1
4
1
25000
5
2
323.15
5
1
879.1
4
1
25000
5
2
328.15
5
1
874
4
1
25000
5
2
333.15
5
1
869.2
4
1
25000
5
2
338.15
5
1
863.6
4
1
25000
5
2
343.15
5
1
859.1
4
1
25000
5
2
348.15
5
1
854
4
1
25000
5
2
353.15
5
1
848.9
4
1
25000
5
2
363.15
5
1
839.1
4
1
25000
5
2
373.15
5
1
829
4
1
25000
5
2
383.15
5
1
818.7
4
1
25000
5
2
393.15
5
1
808
4
1
30000
5
2
298.15
5
1
908.9
4
1
30000
5
2
303.15
5
1
904
4
1
30000
5
2
308.15
5
1
899.2
4
1
30000
5
2
313.15
5
1
894.4
4
1
30000
5
2
318.15
5
1
889.1
4
1
30000
5
2
323.15
5
1
884.3
4
1
30000
5
2
328.15
5
1
879.4
4
1
30000
5
2
333.15
5
1
874.8
4
1
30000
5
2
338.15
5
1
869.9
4
1
30000
5
2
343.15
5
1
865
4
1
30000
5
2
348.15
5
1
860.1
4
1
30000
5
2
353.15
5
1
855.3
4
1
30000
5
2
363.15
5
1
844.8
4
1
30000
5
2
373.15
5
1
834.9
4
1
30000
5
2
383.15
5
1
825
4
1
30000
5
2
393.15
5
1
814.7
4
1
35000
5
2
298.15
5
1
913.6
4
1
35000
5
2
303.15
5
1
908.9
4
1
35000
5
2
308.15
5
1
904.2
4
1
35000
5
2
313.15
5
1
899.5
4
1
35000
5
2
318.15
5
1
894.3
4
1
35000
5
2
323.15
5
1
889.7
4
1
35000
5
2
328.15
5
1
884.9
4
1
35000
5
2
333.15
5
1
880.6
4
1
35000
5
2
338.15
5
1
875.8
4
1
35000
5
2
343.15
5
1
871
4
1
35000
5
2
348.15
5
1
866.3
4
1
35000
5
2
353.15
5
1
861.6
4
1
35000
5
2
363.15
5
1
850.2
4
1
35000
5
2
373.15
5
1
840.6
4
1
35000
5
2
383.15
5
1
830.9
4
1
35000
5
2
393.15
5
1
820.9
4
4
1
Principal objective of the work
VN
TRC
2/20/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
Liquid
1
Pressure, kPa
1
Author
2
Temperature, K
1
Author
1
100
3
2
298.15
5
1
873.3
4
1
100
3
2
303.15
5
1
868.1
4
1
100
3
2
308.15
5
1
862.6
4
1
100
3
2
313.15
5
1
857.3
4
1
100
3
2
318.15
5
1
851.9
4
1
100
3
2
323.15
5
1
846.7
4
1
100
3
2
328.15
5
1
841.4
4
1
100
3
2
333.15
5
1
835.8
4
1
100
3
2
338.15
5
1
830.3
4
1
100
3
2
343.15
5
1
824.8
4
1
100
3
2
348.15
5
1
819.1
4
1
100
3
2
353.15
5
1
813.5
4
1
100
3
2
363.15
5
1
799.9
4
1
100
3
2
373.15
5
1
788.5
4
1
100
3
2
383.15
5
1
776.9
4
1
100
3
2
393.15
5
1
765.1
4
1
1000
4
2
298.15
5
1
874.1
4
1
1000
4
2
303.15
5
1
868.9
4
1
1000
4
2
308.15
5
1
863.5
4
1
1000
4
2
313.15
5
1
858.2
4
1
1000
4
2
318.15
5
1
852.8
4
1
1000
4
2
323.15
5
1
847.4
4
1
1000
4
2
328.15
5
1
842
4
1
1000
4
2
333.15
5
1
837
4
1
1000
4
2
338.15
5
1
831.5
4
1
1000
4
2
343.15
5
1
825.9
4
1
1000
4
2
348.15
5
1
820.3
4
1
1000
4
2
353.15
5
1
814.7
4
1
1000
4
2
363.15
5
1
801.4
4
1
1000
4
2
373.15
5
1
790.1
4
1
1000
4
2
383.15
5
1
778.6
4
1
1000
4
2
393.15
5
1
766.9
4
1
2000
4
2
298.15
5
1
875
4
1
2000
4
2
303.15
5
1
869.8
4
1
2000
4
2
308.15
5
1
864.4
4
1
2000
4
2
313.15
5
1
859.1
4
1
2000
4
2
318.15
5
1
853.8
4
1
2000
4
2
323.15
5
1
848.4
4
1
2000
4
2
328.15
5
1
843.3
4
1
2000
4
2
333.15
5
1
838.1
4
1
2000
4
2
338.15
5
1
832.6
4
1
2000
4
2
343.15
5
1
827.1
4
1
2000
4
2
348.15
5
1
821.6
4
1
2000
4
2
353.15
5
1
816.1
4
1
2000
4
2
363.15
5
1
803
4
1
2000
4
2
373.15
5
1
791.7
4
1
2000
4
2
383.15
5
1
780.4
4
1
2000
4
2
393.15
5
1
768.8
4
1
3000
4
2
298.15
5
1
875.9
4
1
3000
4
2
303.15
5
1
870.7
4
1
3000
4
2
308.15
5
1
865.3
4
1
3000
4
2
313.15
5
1
860.1
4
1
3000
4
2
318.15
5
1
854.8
4
1
3000
4
2
323.15
5
1
849.5
4
1
3000
4
2
328.15
5
1
844.5
4
1
3000
4
2
333.15
5
1
839.2
4
1
3000
4
2
338.15
5
1
833.8
4
1
3000
4
2
343.15
5
1
828.3
4
1
3000
4
2
348.15
5
1
822.9
4
1
3000
4
2
353.15
5
1
817.4
4
1
3000
4
2
363.15
5
1
804.5
4
1
3000
4
2
373.15
5
1
793.4
4
1
3000
4
2
383.15
5
1
782.2
4
1
3000
4
2
393.15
5
1
770.8
4
1
3100
4
2
298.15
5
1
876
4
1
3100
4
2
303.15
5
1
870.7
4
1
3100
4
2
308.15
5
1
865.4
4
1
3100
4
2
313.15
5
1
860.2
4
1
3100
4
2
318.15
5
1
854.9
4
1
3100
4
2
323.15
5
1
849.6
4
1
3100
4
2
328.15
5
1
844.6
4
1
3100
4
2
333.15
5
1
839.3
4
1
3100
4
2
338.15
5
1
833.9
4
1
3100
4
2
343.15
5
1
828.4
4
1
3100
4
2
348.15
5
1
823
4
1
3100
4
2
353.15
5
1
817.5
4
1
3100
4
2
363.15
5
1
804.7
4
1
3100
4
2
373.15
5
1
793.6
4
1
3100
4
2
383.15
5
1
782.4
4
1
3100
4
2
393.15
5
1
771
4
1
5000
4
2
298.15
5
1
877.5
4
1
5000
4
2
303.15
5
1
872.4
4
1
5000
4
2
308.15
5
1
867.1
4
1
5000
4
2
313.15
5
1
861.9
4
1
5000
4
2
318.15
5
1
856.7
4
1
5000
4
2
323.15
5
1
851.7
4
1
5000
4
2
328.15
5
1
846.6
4
1
5000
4
2
333.15
5
1
841.2
4
1
5000
4
2
338.15
5
1
835.9
4
1
5000
4
2
343.15
5
1
830.7
4
1
5000
4
2
348.15
5
1
825.1
4
1
5000
4
2
353.15
5
1
819.8
4
1
5000
4
2
363.15
5
1
807.9
4
1
5000
4
2
373.15
5
1
796.8
4
1
5000
4
2
383.15
5
1
785.5
4
1
5000
4
2
393.15
5
1
774.5
4
1
10000
5
2
298.15
5
1
881.5
4
1
10000
5
2
303.15
5
1
876.5
4
1
10000
5
2
308.15
5
1
871.4
4
1
10000
5
2
313.15
5
1
866.3
4
1
10000
5
2
318.15
5
1
861.3
4
1
10000
5
2
323.15
5
1
856.7
4
1
10000
5
2
328.15
5
1
851.5
4
1
10000
5
2
333.15
5
1
846.3
4
1
10000
5
2
338.15
5
1
841.2
4
1
10000
5
2
343.15
5
1
836.2
4
1
10000
5
2
348.15
5
1
830.9
4
1
10000
5
2
353.15
5
1
825.7
4
1
10000
5
2
363.15
5
1
814.4
4
1
10000
5
2
373.15
5
1
804
4
1
10000
5
2
383.15
5
1
793.5
4
1
10000
5
2
393.15
5
1
783.1
4
1
15000
5
2
298.15
5
1
885.3
4
1
15000
5
2
303.15
5
1
880.4
4
1
15000
5
2
308.15
5
1
875.5
4
1
15000
5
2
313.15
5
1
870.5
4
1
15000
5
2
318.15
5
1
865.8
4
1
15000
5
2
323.15
5
1
861.1
4
1
15000
5
2
328.15
5
1
856.2
4
1
15000
5
2
333.15
5
1
851.1
4
1
15000
5
2
338.15
5
1
846.2
4
1
15000
5
2
343.15
5
1
841.4
4
1
15000
5
2
348.15
5
1
836.2
4
1
15000
5
2
353.15
5
1
831.2
4
1
15000
5
2
363.15
5
1
820.7
4
1
15000
5
2
373.15
5
1
810.8
4
1
15000
5
2
383.15
5
1
800.8
4
1
15000
5
2
393.15
5
1
790.9
4
1
20000
5
2
298.15
5
1
889
4
1
20000
5
2
303.15
5
1
884.1
4
1
20000
5
2
308.15
5
1
879.4
4
1
20000
5
2
313.15
5
1
874.5
4
1
20000
5
2
318.15
5
1
869.9
4
1
20000
5
2
323.15
5
1
865.4
4
1
20000
5
2
328.15
5
1
860.5
4
1
20000
5
2
333.15
5
1
855.6
4
1
20000
5
2
338.15
5
1
850.8
4
1
20000
5
2
343.15
5
1
846.1
4
1
20000
5
2
348.15
5
1
841.1
4
1
20000
5
2
353.15
5
1
836.3
4
1
20000
5
2
363.15
5
1
826.7
4
1
20000
5
2
373.15
5
1
817.2
4
1
20000
5
2
383.15
5
1
807.5
4
1
20000
5
2
393.15
5
1
798
4
1
25000
5
2
298.15
5
1
892.5
4
1
25000
5
2
303.15
5
1
887.8
4
1
25000
5
2
308.15
5
1
883.1
4
1
25000
5
2
313.15
5
1
878.4
4
1
25000
5
2
318.15
5
1
874.1
4
1
25000
5
2
323.15
5
1
869.4
4
1
25000
5
2
328.15
5
1
864.8
4
1
25000
5
2
333.15
5
1
860.1
4
1
25000
5
2
338.15
5
1
855.5
4
1
25000
5
2
343.15
5
1
850.1
4
1
25000
5
2
348.15
5
1
846
4
1
25000
5
2
353.15
5
1
841.4
4
1
25000
5
2
363.15
5
1
832.4
4
1
25000
5
2
373.15
5
1
823.1
4
1
25000
5
2
383.15
5
1
813.8
4
1
25000
5
2
393.15
5
1
804.6
4
1
30000
5
2
298.15
5
1
896.9
4
1
30000
5
2
303.15
5
1
892.3
4
1
30000
5
2
308.15
5
1
887.8
4
1
30000
5
2
313.15
5
1
883.2
4
1
30000
5
2
318.15
5
1
879
4
1
30000
5
2
323.15
5
1
874.5
4
1
30000
5
2
328.15
5
1
870
4
1
30000
5
2
333.15
5
1
865.4
4
1
30000
5
2
338.15
5
1
861
4
1
30000
5
2
343.15
5
1
855.7
4
1
30000
5
2
348.15
5
1
851.8
4
1
30000
5
2
353.15
5
1
847.4
4
1
30000
5
2
363.15
5
1
837.7
4
1
30000
5
2
373.15
5
1
828.7
4
1
30000
5
2
383.15
5
1
819.6
4
1
30000
5
2
393.15
5
1
810.7
4
1
35000
5
2
298.15
5
1
901.4
4
1
35000
5
2
303.15
5
1
896.9
4
1
35000
5
2
308.15
5
1
892.5
4
1
35000
5
2
313.15
5
1
888.1
4
1
35000
5
2
318.15
5
1
884.1
4
1
35000
5
2
323.15
5
1
879.7
4
1
35000
5
2
328.15
5
1
875.3
4
1
35000
5
2
333.15
5
1
870.8
4
1
35000
5
2
338.15
5
1
866.5
4
1
35000
5
2
343.15
5
1
861.8
4
1
35000
5
2
348.15
5
1
857.7
4
1
35000
5
2
353.15
5
1
853.4
4
1
35000
5
2
363.15
5
1
842.7
4
1
35000
5
2
373.15
5
1
834
4
1
35000
5
2
383.15
5
1
825.2
4
1
35000
5
2
393.15
5
1
816.6
4
5
1
Principal objective of the work
VN
TRC
2/20/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
Liquid
1
Pressure, kPa
1
Author
2
Temperature, K
1
Author
1
100
3
2
298.15
5
1
870.7
4
1
100
3
2
303.15
5
1
865.5
4
1
100
3
2
308.15
5
1
860.3
4
1
100
3
2
313.15
5
1
855
4
1
100
3
2
318.15
5
1
849.8
4
1
100
3
2
323.15
5
1
844.4
4
1
100
3
2
328.15
5
1
839.1
4
1
100
3
2
333.15
5
1
833.7
4
1
100
3
2
338.15
5
1
828.4
4
1
100
3
2
343.15
5
1
823
4
1
100
3
2
348.15
5
1
817.7
4
1
100
3
2
353.15
5
1
812.2
4
1
100
3
2
363.15
5
1
801.2
4
1
100
3
2
373.15
5
1
790.7
4
1
100
3
2
383.15
5
1
779.9
4
1
100
3
2
393.15
5
1
769
4
1
1000
4
2
298.15
5
1
871.5
4
1
1000
4
2
303.15
5
1
866.4
4
1
1000
4
2
308.15
5
1
861.2
4
1
1000
4
2
313.15
5
1
855.9
4
1
1000
4
2
318.15
5
1
850.6
4
1
1000
4
2
323.15
5
1
845.3
4
1
1000
4
2
328.15
5
1
840
4
1
1000
4
2
333.15
5
1
834.7
4
1
1000
4
2
338.15
5
1
829.5
4
1
1000
4
2
343.15
5
1
824.1
4
1
1000
4
2
348.15
5
1
818.7
4
1
1000
4
2
353.15
5
1
813.3
4
1
1000
4
2
363.15
5
1
802.5
4
1
1000
4
2
373.15
5
1
792
4
1
1000
4
2
383.15
5
1
781.3
4
1
1000
4
2
393.15
5
1
770.5
4
1
2000
4
2
298.15
5
1
872.4
4
1
2000
4
2
303.15
5
1
867.4
4
1
2000
4
2
308.15
5
1
862.1
4
1
2000
4
2
313.15
5
1
856.9
4
1
2000
4
2
318.15
5
1
851.7
4
1
2000
4
2
323.15
5
1
846.4
4
1
2000
4
2
328.15
5
1
841.1
4
1
2000
4
2
333.15
5
1
836
4
1
2000
4
2
338.15
5
1
830.7
4
1
2000
4
2
343.15
5
1
825.3
4
1
2000
4
2
348.15
5
1
820
4
1
2000
4
2
353.15
5
1
814.6
4
1
2000
4
2
363.15
5
1
803.9
4
1
2000
4
2
373.15
5
1
793.5
4
1
2000
4
2
383.15
5
1
783
4
1
2000
4
2
393.15
5
1
772.3
4
1
2780
4
2
298.15
5
1
873
4
1
2780
4
2
303.15
5
1
868.1
4
1
2780
4
2
308.15
5
1
862.9
4
1
2780
4
2
313.15
5
1
857.7
4
1
2780
4
2
318.15
5
1
852.4
4
1
2780
4
2
323.15
5
1
847.2
4
1
2780
4
2
328.15
5
1
842
4
1
2780
4
2
333.15
5
1
836.9
4
1
2780
4
2
338.15
5
1
831.5
4
1
2780
4
2
343.15
5
1
826.2
4
1
2780
4
2
348.15
5
1
821
4
1
2780
4
2
353.15
5
1
815.6
4
1
2780
4
2
363.15
5
1
805
4
1
2780
4
2
373.15
5
1
794.7
4
1
2780
4
2
383.15
5
1
784.2
4
1
2780
4
2
393.15
5
1
773.6
4
1
3000
4
2
298.15
5
1
873.2
4
1
3000
4
2
303.15
5
1
868.3
4
1
3000
4
2
308.15
5
1
863.1
4
1
3000
4
2
313.15
5
1
857.9
4
1
3000
4
2
318.15
5
1
852.7
4
1
3000
4
2
323.15
5
1
847.4
4
1
3000
4
2
328.15
5
1
842.3
4
1
3000
4
2
333.15
5
1
837.1
4
1
3000
4
2
338.15
5
1
831.8
4
1
3000
4
2
343.15
5
1
826.5
4
1
3000
4
2
348.15
5
1
821.3
4
1
3000
4
2
353.15
5
1
815.9
4
1
3000
4
2
363.15
5
1
805.5
4
1
3000
4
2
373.15
5
1
795
4
1
3000
4
2
383.15
5
1
784.5
4
1
3000
4
2
393.15
5
1
774.1
4
1
5000
4
2
298.15
5
1
875.1
4
1
5000
4
2
303.15
5
1
870.1
4
1
5000
4
2
308.15
5
1
865
4
1
5000
4
2
313.15
5
1
859.9
4
1
5000
4
2
318.15
5
1
854.6
4
1
5000
4
2
323.15
5
1
849.4
4
1
5000
4
2
328.15
5
1
844.4
4
1
5000
4
2
333.15
5
1
839.3
4
1
5000
4
2
338.15
5
1
834
4
1
5000
4
2
343.15
5
1
828.8
4
1
5000
4
2
348.15
5
1
823.7
4
1
5000
4
2
353.15
5
1
818.4
4
1
5000
4
2
363.15
5
1
808.1
4
1
5000
4
2
373.15
5
1
797.9
4
1
5000
4
2
383.15
5
1
787.6
4
1
5000
4
2
393.15
5
1
777.4
4
1
10000
5
2
298.15
5
1
879.4
4
1
10000
5
2
303.15
5
1
874.5
4
1
10000
5
2
308.15
5
1
869.5
4
1
10000
5
2
313.15
5
1
864.5
4
1
10000
5
2
318.15
5
1
859.4
4
1
10000
5
2
323.15
5
1
854.3
4
1
10000
5
2
328.15
5
1
849.4
4
1
10000
5
2
333.15
5
1
844.5
4
1
10000
5
2
338.15
5
1
839.4
4
1
10000
5
2
343.15
5
1
834.4
4
1
10000
5
2
348.15
5
1
829.4
4
1
10000
5
2
353.15
5
1
824.3
4
1
10000
5
2
363.15
5
1
814.6
4
1
10000
5
2
373.15
5
1
804.8
4
1
10000
5
2
383.15
5
1
795
4
1
10000
5
2
393.15
5
1
785.1
4
1
15000
5
2
298.15
5
1
883.4
4
1
15000
5
2
303.15
5
1
878.7
4
1
15000
5
2
308.15
5
1
873.8
4
1
15000
5
2
313.15
5
1
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4
1
15000
5
2
318.15
5
1
863.9
4
1
15000
5
2
323.15
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1
859
4
1
15000
5
2
328.15
5
1
854.2
4
1
15000
5
2
333.15
5
1
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4
1
15000
5
2
338.15
5
1
844.5
4
1
15000
5
2
343.15
5
1
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4
1
15000
5
2
348.15
5
1
834.8
4
1
15000
5
2
353.15
5
1
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4
1
15000
5
2
363.15
5
1
820.5
4
1
15000
5
2
373.15
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1
810.9
4
1
15000
5
2
383.15
5
1
801.5
4
1
15000
5
2
393.15
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1
791.6
4
1
20000
5
2
298.15
5
1
887.3
4
1
20000
5
2
303.15
5
1
882.6
4
1
20000
5
2
308.15
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1
877.8
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1
20000
5
2
313.15
5
1
873
4
1
20000
5
2
318.15
5
1
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4
1
20000
5
2
323.15
5
1
863.4
4
1
20000
5
2
328.15
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1
858.7
4
1
20000
5
2
333.15
5
1
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1
20000
5
2
338.15
5
1
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4
1
20000
5
2
343.15
5
1
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4
1
20000
5
2
348.15
5
1
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4
1
20000
5
2
353.15
5
1
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4
1
20000
5
2
363.15
5
1
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4
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20000
5
2
373.15
5
1
816.7
4
1
20000
5
2
383.15
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1
807.6
4
1
20000
5
2
393.15
5
1
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1
25000
5
2
298.15
5
1
891
4
1
25000
5
2
303.15
5
1
886.5
4
1
25000
5
2
308.15
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1
881.8
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1
25000
5
2
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5
1
877
4
1
25000
5
2
318.15
5
1
872.3
4
1
25000
5
2
323.15
5
1
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4
1
25000
5
2
328.15
5
1
863
4
1
25000
5
2
333.15
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1
858.6
4
1
25000
5
2
338.15
5
1
853.9
4
1
25000
5
2
343.15
5
1
849.2
4
1
25000
5
2
348.15
5
1
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4
1
25000
5
2
353.15
5
1
840
4
1
25000
5
2
363.15
5
1
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4
1
25000
5
2
373.15
5
1
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4
1
25000
5
2
383.15
5
1
813.4
4
1
25000
5
2
393.15
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1
803.5
4
1
30000
5
2
298.15
5
1
894.6
4
1
30000
5
2
303.15
5
1
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4
1
30000
5
2
308.15
5
1
885.6
4
1
30000
5
2
313.15
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1
880.9
4
1
30000
5
2
318.15
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1
876.3
4
1
30000
5
2
323.15
5
1
871.7
4
1
30000
5
2
328.15
5
1
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1
30000
5
2
333.15
5
1
862.9
4
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30000
5
2
338.15
5
1
858.2
4
1
30000
5
2
343.15
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1
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4
1
30000
5
2
348.15
5
1
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4
1
30000
5
2
353.15
5
1
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4
1
30000
5
2
363.15
5
1
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4
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5
2
373.15
5
1
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4
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5
2
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1
818.9
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5
2
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1
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4
1
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2
298.15
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1
898.1
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1
35000
5
2
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1
893.8
4
1
35000
5
2
308.15
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1
889.2
4
1
35000
5
2
313.15
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1
884.6
4
1
35000
5
2
318.15
5
1
880.1
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1
35000
5
2
323.15
5
1
875.5
4
1
35000
5
2
328.15
5
1
871.1
4
1
35000
5
2
333.15
5
1
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4
1
35000
5
2
338.15
5
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862.4
4
1
35000
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2
343.15
5
1
858
4
1
35000
5
2
348.15
5
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4
1
35000
5
2
353.15
5
1
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1
35000
5
2
363.15
5
1
840.8
4
1
35000
5
2
373.15
5
1
832.3
4
1
35000
5
2
383.15
5
1
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4
1
35000
5
2
393.15
5
1
814
4