2
0
2009
abd
saf
0
journal
Original
Abdulagatov, I. M.[Ilmutdin M.]
Safarov, J. T.[Javid T.]
Guliyev, T. A.[Tavakkul A.]
Shahverdiyev, A. N.[Astan N.]
Hassel, E. P.[Egon P.]
J. Chem. Eng. Data
2009
2009-02-25
High Temperature and High Pressure Volumetric (Density and Apparent Molar Volumes) Properties of (CaCl2 + C2H5OH) Solutions
The (p, F, T) and some derived volumetric properties such as apparent molar volumes Vo of CaCl2 in ethanol, isothermal compressibility, and thermal expansion coefficients of (CaCl2 + C2H5OH) solutions at T ) (298.15 to 398.15) K and pressures up to p ) 40 MPa are reported. The density measurements were made at seven molalities of m ) (0.09327, 0.17427, 0.43788, 0.68992, 0.98955, 1.26564, and 1.55045) mol * kg-1 of CaCl2. An empirical correlation for the density of (CaCl2 + C2H5OH) as a function of pressure, temperature, and molality has been developed. This equation of state was used to calculate other volumetric properties such as isothermal compressibility and thermal expansion coefficients. The derived values of apparent molar volumes were extrapolated to zero concentration to calculate the values of apparent molar volumes (or partial molar volumes) at infinite dilution.
10.1021/je800234h
54
248-255
1
calcium chloride
CaCl2
1
Commercial source
1
99.8
3
Stated by supplier
2
Dried by oven heating
Dried by vacuum heating
2
ethanol
C2H6O
1
Commercial source
1
99.8
3
Stated by supplier
2
De-gassed by freezing and melting in vacuum
2
99.9
3
Gas chromatography
2
.00005
1
Karl Fischer titration
2
1
1
1
Principal objective of the work
KRP
TRC
2/13/2009
1
Mass density, kg/m3
Vibrating tube method
Liquid
Direct value, X
1
Author
Liquid
1
Molality, mol/kg
1
Liquid
2
2
Temperature, K
1
Author
3
Pressure, kPa
1
Author
1
.09327
4
2
298.15
5
3
480
3
1
793.4
5
1
.15868
1
.09327
4
2
298.15
5
3
5060
4
1
797.34
5
1
.159468
1
.09327
4
2
298.15
5
3
10030
5
1
801.45
5
1
.16029
1
.09327
4
2
298.15
5
3
15470
5
1
805.77
5
1
.161154
1
.09327
4
2
298.15
5
3
20640
5
1
809.69
5
1
.161938
1
.09327
4
2
298.15
5
3
25390
5
1
813.15
5
1
.16263
1
.09327
4
2
298.15
5
3
30190
5
1
816.48
5
1
.163296
1
.09327
4
2
298.15
5
3
35640
5
1
820.09
5
1
.164018
1
.09327
4
2
298.15
5
3
39920
5
1
822.78
5
1
.164556
1
.09327
4
2
323.15
5
3
150
3
1
771.32
5
1
.154264
1
.09327
4
2
323.15
5
3
5240
4
1
776.5
5
1
.1553
1
.09327
4
2
323.15
5
3
10340
5
1
781.44
5
1
.156288
1
.09327
4
2
323.15
5
3
15780
5
1
786.43
5
1
.157286
1
.09327
4
2
323.15
5
3
20980
5
1
790.93
5
1
.158186
1
.09327
4
2
323.15
5
3
25680
5
1
794.77
5
1
.158954
1
.09327
4
2
323.15
5
3
30390
5
1
798.4
5
1
.15968
1
.09327
4
2
323.15
5
3
35870
5
1
802.35
5
1
.16047
1
.09327
4
2
323.15
5
3
39860
5
1
805.04
5
1
.161008
1
.09327
4
2
348.15
5
3
750
3
1
748.39
5
1
.149678
1
.09327
4
2
348.15
5
3
5620
4
1
754.25
5
1
.15085
1
.09327
4
2
348.15
5
3
10820
5
1
760.15
5
1
.15203
1
.09327
4
2
348.15
5
3
15380
5
1
765.02
5
1
.153004
1
.09327
4
2
348.15
5
3
20430
5
1
770.09
5
1
.154018
1
.09327
4
2
348.15
5
3
25160
5
1
774.52
5
1
.154904
1
.09327
4
2
348.15
5
3
30480
5
1
779.14
5
1
.155828
1
.09327
4
2
348.15
5
3
35410
5
1
783.08
5
1
.156616
1
.09327
4
2
348.15
5
3
39260
5
1
785.92
5
1
.157184
1
.09327
4
2
373.15
5
3
370
3
1
722.5
5
1
.1445
1
.09327
4
2
373.15
5
3
5180
4
1
729.16
5
1
.145832
1
.09327
4
2
373.15
5
3
10480
5
1
736.08
5
1
.147216
1
.09327
4
2
373.15
5
3
15720
5
1
742.49
5
1
.148498
1
.09327
4
2
373.15
5
3
20280
5
1
747.72
5
1
.149544
1
.09327
4
2
373.15
5
3
25670
5
1
753.48
5
1
.150696
1
.09327
4
2
373.15
5
3
30290
5
1
758.06
5
1
.151612
1
.09327
4
2
373.15
5
3
35420
5
1
762.76
5
1
.152552
1
.09327
4
2
373.15
5
3
39910
5
1
766.53
5
1
.153306
1
.09327
4
2
398.15
5
3
680
3
1
692.59
5
1
.138518
1
.09327
4
2
398.15
5
3
5100
4
1
700.41
5
1
.140082
1
.09327
4
2
398.15
5
3
10080
5
1
708.63
5
1
.141726
1
.09327
4
2
398.15
5
3
15410
5
1
716.75
5
1
.14335
1
.09327
4
2
398.15
5
3
20030
5
1
723.21
5
1
.144642
1
.09327
4
2
398.15
5
3
25060
5
1
729.63
5
1
.145926
1
.09327
4
2
398.15
5
3
30170
5
1
735.52
5
1
.147104
1
.09327
4
2
398.15
5
3
35180
5
1
740.65
5
1
.14813
1
.09327
4
2
398.15
5
3
39920
5
1
744.93
5
1
.148986
1
.17427
5
2
298.15
5
3
280
3
1
800.14
5
1
.160028
1
.17427
5
2
298.15
5
3
6580
4
1
804.98
5
1
.160996
1
.17427
5
2
298.15
5
3
11330
5
1
808.85
5
1
.16177
1
.17427
5
2
298.15
5
3
15720
5
1
812.29
5
1
.162458
1
.17427
5
2
298.15
5
3
20490
5
1
815.89
5
1
.163178
1
.17427
5
2
298.15
5
3
25820
5
1
819.73
5
1
.163946
1
.17427
5
2
298.15
5
3
31460
5
1
823.58
5
1
.164716
1
.17427
5
2
298.15
5
3
35340
5
1
826.11
5
1
.165222
1
.17427
5
2
298.15
5
3
40180
5
1
829.13
5
1
.165826
1
.17427
5
2
323.15
5
3
240
3
1
777.83
5
1
.155566
1
.17427
5
2
323.15
5
3
5060
4
1
782.74
5
1
.156548
1
.17427
5
2
323.15
5
3
10480
5
1
787.98
5
1
.157596
1
.17427
5
2
323.15
5
3
15620
5
1
792.67
5
1
.158534
1
.17427
5
2
323.15
5
3
20640
5
1
796.99
5
1
.159398
1
.17427
5
2
323.15
5
3
25870
5
1
801.22
5
1
.160244
1
.17427
5
2
323.15
5
3
30380
5
1
804.64
5
1
.160928
1
.17427
5
2
323.15
5
3
35920
5
1
808.56
5
1
.161712
1
.17427
5
2
323.15
5
3
39940
5
1
811.21
5
1
.162242
1
.17427
5
2
348.15
5
3
890
3
1
755.18
5
1
.151036
1
.17427
5
2
348.15
5
3
5090
4
1
760.16
5
1
.152032
1
.17427
5
2
348.15
5
3
10480
5
1
766.21
5
1
.153242
1
.17427
5
2
348.15
5
3
15760
5
1
771.77
5
1
.154354
1
.17427
5
2
348.15
5
3
20480
5
1
776.42
5
1
.155284
1
.17427
5
2
348.15
5
3
25620
5
1
781.15
5
1
.15623
1
.17427
5
2
348.15
5
3
30420
5
1
785.25
5
1
.15705
1
.17427
5
2
348.15
5
3
35860
5
1
789.53
5
1
.157906
1
.17427
5
2
348.15
5
3
39970
5
1
792.5
5
1
.1585
1
.17427
5
2
373.15
5
3
680
3
1
728.72
5
1
.145744
1
.17427
5
2
373.15
5
3
5060
4
1
735.26
5
1
.147052
1
.17427
5
2
373.15
5
3
10740
5
1
743.09
5
1
.148618
1
.17427
5
2
373.15
5
3
15250
5
1
748.79
5
1
.149758
1
.17427
5
2
373.15
5
3
20640
5
1
754.98
5
1
.150996
1
.17427
5
2
373.15
5
3
25180
5
1
759.68
5
1
.151936
1
.17427
5
2
373.15
5
3
30410
5
1
764.51
5
1
.152902
1
.17427
5
2
373.15
5
3
35870
5
1
768.88
5
1
.153776
1
.17427
5
2
373.15
5
3
39740
5
1
771.57
5
1
.154314
1
.17427
5
2
398.15
5
3
1030
4
1
700.75
5
1
.14015
1
.17427
5
2
398.15
5
3
5070
4
1
707.51
5
1
.141502
1
.17427
5
2
398.15
5
3
10540
5
1
716.08
5
1
.143216
1
.17427
5
2
398.15
5
3
15290
5
1
722.99
5
1
.144598
1
.17427
5
2
398.15
5
3
20140
5
1
729.54
5
1
.145908
1
.17427
5
2
398.15
5
3
24980
5
1
735.56
5
1
.147112
1
.17427
5
2
398.15
5
3
30780
5
1
742.1
5
1
.14842
1
.17427
5
2
398.15
5
3
35460
5
1
746.84
5
1
.149368
1
.17427
5
2
398.15
5
3
39790
5
1
750.79
5
1
.150158
1
.43788
5
2
298.15
5
3
1020
4
1
820.65
5
1
.16413
1
.43788
5
2
298.15
5
3
5030
4
1
824.03
5
1
.164806
1
.43788
5
2
298.15
5
3
10450
5
1
828.43
5
1
.165686
1
.43788
5
2
298.15
5
3
15480
5
1
832.33
5
1
.166466
1
.43788
5
2
298.15
5
3
20460
5
1
836.02
5
1
.167204
1
.43788
5
2
298.15
5
3
25750
5
1
839.75
5
1
.16795
1
.43788
5
2
298.15
5
3
30640
5
1
843.03
5
1
.168606
1
.43788
5
2
298.15
5
3
35830
5
1
846.33
5
1
.169266
1
.43788
5
2
298.15
5
3
39970
5
1
848.83
5
1
.169766
1
.43788
5
2
323.15
5
3
450
3
1
798.42
5
1
.159684
1
.43788
5
2
323.15
5
3
4980
4
1
802.82
5
1
.160564
1
.43788
5
2
323.15
5
3
9780
4
1
807.29
5
1
.161458
1
.43788
5
2
323.15
5
3
15060
5
1
811.96
5
1
.162392
1
.43788
5
2
323.15
5
3
20040
5
1
816.13
5
1
.163226
1
.43788
5
2
323.15
5
3
24870
5
1
819.96
5
1
.163992
1
.43788
5
2
323.15
5
3
30020
5
1
823.82
5
1
.164764
1
.43788
5
2
323.15
5
3
35150
5
1
827.42
5
1
.165484
1
.43788
5
2
323.15
5
3
39760
5
1
830.46
5
1
.166092
1
.43788
5
2
348.15
5
3
620
3
1
774.92
5
1
.154984
1
.43788
5
2
348.15
5
3
5130
4
1
780.06
5
1
.156012
1
.43788
5
2
348.15
5
3
10240
5
1
785.57
5
1
.157114
1
.43788
5
2
348.15
5
3
15310
5
1
790.73
5
1
.158146
1
.43788
5
2
348.15
5
3
20840
5
1
796.01
5
1
.159202
1
.43788
5
2
348.15
5
3
25040
5
1
799.76
5
1
.159952
1
.43788
5
2
348.15
5
3
30730
5
1
804.51
5
1
.160902
1
.43788
5
2
348.15
5
3
35150
5
1
807.92
5
1
.161584
1
.43788
5
2
348.15
5
3
39380
5
1
810.96
5
1
.162192
1
.43788
5
2
373.15
5
3
940
3
1
749.01
5
1
.149802
1
.43788
5
2
373.15
5
3
5170
4
1
754.76
5
1
.150952
1
.43788
5
2
373.15
5
3
10480
5
1
761.55
5
1
.15231
1
.43788
5
2
373.15
5
3
15190
5
1
767.19
5
1
.153438
1
.43788
5
2
373.15
5
3
20160
5
1
772.75
5
1
.15455
1
.43788
5
2
373.15
5
3
25130
5
1
777.9
5
1
.15558
1
.43788
5
2
373.15
5
3
30240
5
1
782.77
5
1
.156554
1
.43788
5
2
373.15
5
3
35370
5
1
787.22
5
1
.157444
1
.43788
5
2
373.15
5
3
39260
5
1
790.31
5
1
.158062
1
.43788
5
2
398.15
5
3
950
3
1
719.54
5
1
.143908
1
.43788
5
2
398.15
5
3
5380
4
1
726.88
5
1
.145376
1
.43788
5
2
398.15
5
3
10290
5
1
734.49
5
1
.146898
1
.43788
5
2
398.15
5
3
15610
5
1
742.12
5
1
.148424
1
.43788
5
2
398.15
5
3
20480
5
1
748.53
5
1
.149706
1
.43788
5
2
398.15
5
3
25340
5
1
754.4
5
1
.15088
1
.43788
5
2
398.15
5
3
30060
5
1
759.57
5
1
.151914
1
.43788
5
2
398.15
5
3
35180
5
1
764.61
5
1
.152922
1
.43788
5
2
398.15
5
3
39380
5
1
768.3
5
1
.15366
1
.68992
5
2
298.15
5
3
1170
4
1
839.86
5
1
.167972
1
.68992
5
2
298.15
5
3
5010
4
1
843.06
5
1
.168612
1
.68992
5
2
298.15
5
3
11050
5
1
847.88
5
1
.169576
1
.68992
5
2
298.15
5
3
15120
5
1
850.99
5
1
.170198
1
.68992
5
2
298.15
5
3
20130
5
1
854.64
5
1
.170928
1
.68992
5
2
298.15
5
3
25310
5
1
858.24
5
1
.171648
1
.68992
5
2
298.15
5
3
30120
5
1
861.41
5
1
.172282
1
.68992
5
2
298.15
5
3
34210
5
1
863.97
5
1
.172794
1
.68992
5
2
298.15
5
3
39770
5
1
867.27
5
1
.173454
1
.68992
5
2
323.15
5
3
1060
4
1
817.18
5
1
.163436
1
.68992
5
2
323.15
5
3
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4
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2
323.15
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5
1
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1
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3
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1
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1
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3
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5
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3
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3
1
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1
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4
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5
1
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5
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3
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4
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4
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5
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1
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3
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4
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1
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1
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1
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1
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4
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4
1
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1
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1
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20060
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1
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5
2
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25080
5
1
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1
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1
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1
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5
2
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5
3
580
3
1
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4
1
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5
1
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5
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1
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20670
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1
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5
1
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5
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1
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5
1
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5
1
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2
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3
920
3
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5
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5
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4
1
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5
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5
1
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5
1
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5
1
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5
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5
1
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5
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1
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5
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1
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5
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3
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5
1
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5
2
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3
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4
1
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398.15
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4
1
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5
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3
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5
1
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5
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398.15
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3
15290
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1
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398.15
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20410
5
1
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5
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3
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5
1
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5
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398.15
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3
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5
1
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5
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3
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5
1
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5
2
398.15
5
3
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5
1
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5
1
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1
1.26564
6
2
298.15
5
3
260
3
1
881.44
5
1
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6
2
298.15
5
3
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4
1
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6
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3
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5
1
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5
1
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3
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1
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6
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298.15
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3
20080
5
1
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6
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5
1
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5
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6
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3
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5
1
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5
1
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6
2
298.15
5
3
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5
1
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5
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
310
3
1
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5
1
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1
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6
2
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5
3
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4
1
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5
1
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
15410
5
1
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5
1
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6
2
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5
3
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5
1
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5
1
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1
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
39870
5
1
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5
1
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6
2
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5
3
270
3
1
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5
1
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1
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6
2
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5
3
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4
1
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5
1
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6
2
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5
3
10450
5
1
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5
1
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
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5
1
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5
1
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1
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6
2
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5
3
420
3
1
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5
1
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6
2
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5
3
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4
1
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5
1
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1
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6
2
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5
3
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4
1
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5
1
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
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5
1
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5
1
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6
2
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5
3
25410
5
1
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5
1
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6
2
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5
3
29980
5
1
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5
1
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6
2
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5
3
35070
5
1
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5
1
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6
2
373.15
5
3
39970
5
1
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5
1
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1
1.26564
6
2
398.15
5
3
620
3
1
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5
1
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1
1.26564
6
2
398.15
5
3
5180
4
1
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5
1
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1
1.26564
6
2
398.15
5
3
10060
5
1
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5
1
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1
1.26564
6
2
398.15
5
3
15620
5
1
800.09
5
1
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1.26564
6
2
398.15
5
3
20080
5
1
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5
1
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1
1.26564
6
2
398.15
5
3
25640
5
1
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5
1
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1
1.26564
6
2
398.15
5
3
30030
5
1
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5
1
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1
1.26564
6
2
398.15
5
3
35740
5
1
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5
1
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6
2
398.15
5
3
39920
5
1
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5
1
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1
1.55045
6
2
298.15
5
3
210
3
1
901.58
5
1
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1
1.55045
6
2
298.15
5
3
5020
4
1
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5
1
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1.55045
6
2
298.15
5
3
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5
1
909.48
5
1
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6
2
298.15
5
3
15240
5
1
912.94
5
1
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6
2
298.15
5
3
20260
5
1
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5
1
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1
1.55045
6
2
298.15
5
3
25010
5
1
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5
1
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1
1.55045
6
2
298.15
5
3
30420
5
1
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5
1
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1
1.55045
6
2
298.15
5
3
35050
5
1
925.22
5
1
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1
1.55045
6
2
298.15
5
3
39960
5
1
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5
1
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1
1.55045
6
2
323.15
5
3
520
3
1
876.88
5
1
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1
1.55045
6
2
323.15
5
3
5120
4
1
881.08
5
1
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1
1.55045
6
2
323.15
5
3
10740
5
1
885.92
5
1
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1
1.55045
6
2
323.15
5
3
15020
5
1
889.39
5
1
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1
1.55045
6
2
323.15
5
3
20420
5
1
893.5
5
1
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1
1.55045
6
2
323.15
5
3
25310
5
1
896.97
5
1
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1
1.55045
6
2
323.15
5
3
30140
5
1
900.16
5
1
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1
1.55045
6
2
323.15
5
3
35620
5
1
903.49
5
1
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1
1.55045
6
2
323.15
5
3
39980
5
1
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5
1
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1
1.55045
6
2
348.15
5
3
310
3
1
852.87
5
1
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1
1.55045
6
2
348.15
5
3
5210
4
1
858.12
5
1
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1
1.55045
6
2
348.15
5
3
10160
5
1
863.08
5
1
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1
1.55045
6
2
348.15
5
3
15680
5
1
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5
1
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1
1.55045
6
2
348.15
5
3
20640
5
1
872.48
5
1
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1
1.55045
6
2
348.15
5
3
25190
5
1
876.08
5
1
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1
1.55045
6
2
348.15
5
3
30750
5
1
880.1
5
1
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1
1.55045
6
2
348.15
5
3
35290
5
1
883.06
5
1
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1
1.55045
6
2
348.15
5
3
39880
5
1
885.77
5
1
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1
1.55045
6
2
373.15
5
3
390
3
1
828.22
5
1
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1
1.55045
6
2
373.15
5
3
5140
4
1
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5
1
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1
1.55045
6
2
373.15
5
3
10150
5
1
840.15
5
1
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1
1.55045
6
2
373.15
5
3
15290
5
1
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5
1
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1
1.55045
6
2
373.15
5
3
20140
5
1
850.48
5
1
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1
1.55045
6
2
373.15
5
3
25750
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1
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1
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1
1.55045
6
2
373.15
5
3
30140
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1
858.93
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1
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1
1.55045
6
2
373.15
5
3
35480
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1
862.67
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1
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1.55045
6
2
373.15
5
3
39970
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1
865.39
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1
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1
1.55045
6
2
398.15
5
3
740
3
1
801.26
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1
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1.55045
6
2
398.15
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3
5470
4
1
808.33
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1
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1.55045
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2
398.15
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3
10460
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1
815.02
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1
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1.55045
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2
398.15
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3
15620
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1
821.29
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1
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1.55045
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2
398.15
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3
20140
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1
826.33
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1
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1.55045
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2
398.15
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3
25340
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1
831.69
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1
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1.55045
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2
398.15
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3
30470
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1
836.6
5
1
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1.55045
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2
398.15
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3
35830
5
1
841.39
5
1
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1
1.55045
6
2
398.15
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3
39760
5
1
844.7
5
1
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